Stainless Steels
The basic resistance of stainless steel occurs because of its ability to form a protective coating on the metal surface. This coating is a "passive" film which is resistant to further "oxidation" or rusting. The formation of this film is instantaneous in an oxidizing atmosphere such as air, water, or many other fluids that contain oxygen. Once the layer has formed we say that the metal has become "passivated" and the oxidation or "rusting" rate will slow down to less than 0.002" per year (0,05 mm. per year).
Unlike aluminum or silver this passive film is invisible in stainless steel. It is due to the combining of oxygen with the chrome in the stainless to form chrome oxide which is more commonly called "ceramic". This protective oxide or ceramic coating is common to most corrosion resistant materials.
Halogen salts, especially chlorides easily penetrate this passive film and will allow corrosive attack to occur. The halogens are easy to recognize because they end in the letters "ine". Listed in order of their activity they are: fluorine, chlorine, bromine, iodine and astatine. These are the same chemicals that will penetrate Teflon and cause trouble with Teflon coated or encapsulated O-Rings and/ or similar coated materials. Chlorides are one of the most common elements in nature and if that isn't bad enough they are also soluble, active ions; the basis for good electrolytes, the best conditions for corrosion or chemical attack.
Stainless Steels are iron-base alloys containing Chromium. Stainless steels usually contain less than 30% Cr and more than 50% Fe. They attain their stainless characteristics because of the formation of an invisible and adherent chromium-rich oxide surface film. This oxide establishes on the surface and heals itself in the presence of oxygen. Some other alloying elements added to enhance specific characteristics include nickel, molybdenum, copper, titanium, aluminum, silicon, niobium, and nitrogen. Carbon is usually present in amounts ranging from less than 0.03% to over 1.0% in certain martensitic grades. Corrosion resistance and mechanical properties are commonly the principal factors in selecting a grade of stainless steel for a given application.
Technically, stainless steels are commonly divided into five groups:
Martensitic stainless steels are essentially alloys of chromium and carbon that possess a martensitic crystal structure in the hardened condition. They are ferromagnetic, harden able by heat treatments, and are usually less resistant to corrosion than some other grades of stainless steel. Excess carbides may be present to enhance wear resistance or as in the case of knife blades, to maintain cutting edges.
Ferritic stainless steels are chromium containing alloys with Ferritic, body centered cubic (bcc) crystal structures. Chromium content is typically less than 30%. The ferritic stainless steels are ferromagnetic. They may have good ductility and formability, but high-temperature mechanical properties are relatively inferior to the austenitic stainless steels.
The more important stainless for boat is the 300 series. Austenitic stainless steels have an austenitic, face centered cubic (fcc) crystal structure. Austenite is formed through the generous use of austenitizing elements such as nickel, manganese, and nitrogen. Austenitic stainless steels are effectively nonmagnetic in the annealed condition and can be hardened only by cold working. Chromium content typically is in the range of 16 to 26%; nickel content is commonly less than 35%.
Duplex stainless steels are a mixture of bcc ferrite and fcc austenite crystal structures. The percentage each phase is a dependent on the composition and heat treatment. The primary alloying elements are chromium and nickel. Duplex stainless steels generally have similar corrosion resistance to austenitic alloys except they typically have better stress corrosion cracking resistance.
Precipitation hardening stainless steels are chromium-nickel alloys and may be either austenitic or martensitic in the annealed condition. In most cases, precipitation hardening stainless steels attain high strength by precipitation hardening of the martensitic structure.
So, what has all this to do with boats? Plenty, one of the biggest discoveries of counterfeit products in the late 90’s was by the U.S. government in their inventory of nuts and bolts at government vehicle and aircraft repair centers! They found all kinds of fasteners that were counterfeit in grade and substandard materials, etc. What makes you think your stainless supplier hasn’t bought them also? I have come across lots of rusty “stainless” screws and bolts that are also magnetic (high carbon content) on fittings exposed to saltwater and the elements. 316 stainless steel is not magnetic, so when you standing there rummaging through a bin full of screws for that new fitting you’re going to install on deck. First bring a magnet. All the ones that stick to a magnet, you do not want no matter how stainless they look. Second, ensure that fittings and the fasteners will carry the load you will place on it. Go to this Aussie website to check the strength of the fasteners,
http://www.marfas.com/mechanical.html
And this one to find out how tight to make them.
http://www.marfas.com/Ttorque.shtml
Third put lots of good quality marine sealer in that hole, on the threads, etc., You can clean off the excess and be sure your not starting a disaster that may cost you thousands later.
Fourth, if you have a screw, bolt, or nut that constantly seeps out a rust stain, pull it out and check it for water intrusion(not caulked properly) and advanced corrosion( old, rotted, and it maybe failing, fast).
Fifth, read the labels on the cleaning products you are using; remember all those chlorides in nature eat stainless, so why would you want to add more.
Taking care of all those fasteners aboard cuts down the failure of systems, enhances appearance and value, and makes that end of the day clean up lots faster.
WIRES
Did you get a good deal on that nice, shiny, brown copper wire at the auto part store for your boat? I'm sorry to tell you, it just won't last! The copper will be attacked before you crimp the first fitting, then voltage and amperage drop, then maybe corrosion to the point that the wire drops off the terminal and worse case, falls into the bilge. Now, a possible hot wire in water in the bilge starts eating metal, any kind of metal. Engines, shafts, props, thru-hulls, hose clamps, etc. wherever the path of least resistance goes.
Generally speaking, improper wiring on boats abounds. The marine environment is a harsh one, and what may have sufficed on an automobile you tinkered with at one time, is no match for the incessant ravages of the salt water environment. This is especially so on older boats where multiple layers of electrical upgrades left by multiple owners can leave an owner perplexed.
And always make sure that you use marine-grade materials. Marine wire has flexible, multi-stranded, tinned copper conductors. Tinned refers to the silver color coating that protects the wire from corrosion. Marine wire insulation should additionally be oil, water, and heat-resistant. Wire connectors should be double crimp, tinned copper, with a nylon (not vinyl) outer sleeve. Do not use wire nuts or simply twist and tape wire ends together. These methods cannot properly seal the connection, and can vibrate loose, leaving a live wire out of sight just waiting for something to send it arcing.
Solder can be a mixed blessing. Solder and tape connections that don't use mechanical connectors can fail by breaking. A good solder joint is nearly perfect. A bad one can fail completely. On tinned marine grade wire, excellent, reliable, repeatable splices can be made without soldering.
Adhesive-lined heat-shrink tubing is the marine electrician's secret weapon. Properly applied, this stuff will seal out 100 percent of the moisture in a splice. Additionally, it also makes it even harder to pull the splice apart. Beware of thin walled heat shrink tubing that doesn't come with an adhesive. These products will wick in moisture, and are easily damaged.
Butt Splices. You should cut and discard about two inches of wire to give you a new end to work with. First, strip off the length of insulation that will fit into the copper barrel of the butt connector. Use proper wire strippers that remove only the insulation and not the wire strands with it. Next, find the suitably sized nylon coated butt connector for the splice. Yellow is for size 10-12 AWG (American wire gauge), blue is 14-16 AWG, and red is 18-22 AWG. Slide the wire into the connector, making sure no strands are pushed back. The stripped portion of the wire should insert completely into the narrow section of the metal barrel. The nylon sleeve and the wider portion of the barrel should overlap the insulation of the wire. Making sure the wire does not lose this position, crimp the inner narrow barrel first and then the outer wider portion. The crimping should be done with very firm pressure.
Before adding the second wire to the splice, prepare it for the moisture seal. Use a piece of heat shrink that is the proper diameter to freely slide over the connector. Cut a piece long enough to cover the entire splice and overlap the wire insulation by at least a half-inch on each end. Slide the heat shrink over the wire and out of the way of the butt connector. Strip the end of the other wire in the connection. Insert this second wire into the barrel and crimp the connector. Test the connection with a very firm pull. It is better to have to re-splice it now rather than have the connection fail in service. Now slide the heat shrink back over the splice. Using a heat gun, heat the splice evenly by moving the heat source back and forth and around the splice. Once the tubing has shrunk to taken on the shape of the splice and the wire, and the adhesive has flowed out completely around both ends, the splice is complete.
Terminals. The best terminal ends are the closed ring type, which can't vibrate out if the terminal screw loosens. The screw or stud must fit in the ring. If the ring is too large, you will not make good contact, which is what all electrical systems are based upon. If the ring is too small the screw will bind in the ring. Avoid using plug in type male/female connectors. These are referred to as blade or bullet disconnects. These are difficult to seal and they often come apart too easily.
Crimping the terminal end is similar to a butt splice. Strip the wire back the same length as the small section of the barrel plus another 1/16 of an inch. Then slide the heat-shrink tubing over the wire and out of the way before placing the terminal on the end. Slide the wire into the correct size ring terminal until the strands exit the ring side of the terminal by a hair. Crimp the ring end of the sleeve first, then the wire side. Test the crimp with a hearty tug. Then slide the heat shrink tubing over the connector so that it just covers the protruding wires on the ring end of the sleeve and overlaps the insulation on the wire end. Avoid sliding the tubing over the ring area, as this will interfere with the screw contact. Next, heat the tubing just as you did with the butt splice. If any wire strands are visible at the ring end of the sleeve, seal them with an electrical sealant.
The Finishing Touch. Supporting the wire before and after the connector will reduce tension on the splice itself. Either bundle the spliced wire to other wires with ties or use wire clamps to hold the wire to fixed parts of the boat. If two adjacent butt splices must be made, stagger the splices by a couple of inches. Should the wires pull apart, they won't short against each other. In any location where moisture might wick down the wire and into the splice you should form a drip loop. Simply make a bend in the wire that will cause water to drip off of the wire before reaching the splice. After the new wire is run, it should be labeled on both ends.
So now if you add voltage to that rotted copper wire… and remember, a reaction will also occur without the presence of chlorine; but chlorine (that chemical that also eats stainless), a small atom and an excellent oxidizer, greatly accelerates the corrosion process.
Here's a website from the U.S. Coast Guard with electrical requirement mandates for small craft.
http://www.uscgboating.org/SAFETY/boatbuilder/electrical/electrical.htm
and the handbook...
http://www.uscgboating.org/SAFETY/boatbuilder/electrical/electrical.htm
Also, a site I like, providing a real good overview, with specfics, on the total electrical system.
http://www.islandnet.com/~robb/marine.html

So, that shiny brown copper wire maybe a good price but do you really want to reach down into the bilge to redo that float switch at the worse time, or wonder why that navigation lights don’t work, working into the harbor at night, pull the anchor up by hand, and the start or kill switch on the engine won't work, etc.
Hanging by a Thread
I survey to ABYC voluntary “specifications” and at times had to write in my reports that the ball valves on a vessels thru-hull fittings do not comply with those specifications, especially those below the waterline. Some times that’s 20-30 ball valves! So what’s the difference? First, here’s what they look like.
Ball Valves Sea Cocks

That “base” or “plate” at the bottom of the sea cocks is the first difference. Also, most of the ball valves I have seen are “taper” threaded. Tapered threads were designed and invented to help a joint not to leak. That’s great but most thru-hull fittings are straight threads, like these.

So, you screw a straight thread to a tapered ball valve, it goes in a few turns, then won’t go any more, with some sealer it probably will not leak. You notice an inch or two, or maybe four or five between the ball valve and the hull? That’s what I mean by "Hanging by a Thread". A 1 ½” thru-hull fitting maybe have 3/16” wall thickness before it’s threaded, and I don’t know how deep those cuts are in the threading process. You could end up with a nice 1 ½” hole below the waterline with only a 1/8” of wall thickness between you and lots of water. You really don’t want to step on that fitting, or drop anything heavy on it, or yank too hard if the handle is frozen! And if it does fail below the ball valve, just what was the ball valve for? You say you have a bilge pump? That's great, here are some approximate water flow rates for different size holes, just 2 feet below the waterline:
(Head intake) 1" - 950 gallons per hour
(Head discharge) 1 1/2" - 2080 gallons per hour
(Small engine intake) 2" - 6,666 gallons per hour
(Large engine intake) 4" - 26,670 gallons per hour
The idea behind a sea cock is that with a small block under that straight threaded sea cock base or plate shown; you can tighten down all the way to the hull. You end up with a thru-hull fitting “sandwiched” between hull, inside block, and then the bronze base of the sea cock flush to the hull on the inside. You can calculate the amount of thickness and mass thats added. Now that 1 ½” hole, that lets water in, is more than likely, if ever going to break, will be above the sea cock and you can turn that water off. Last thing use a good sealer, NOT ADHESIVE, on that thru-hull fitting? 3M, 5200 is mostly an adhesive, real trouble to get a thru-hull off the hull or to back it out some to reseal? Not going to happen.
Contact me at:
Phone: 808-375-8260
Email: Bob@BoatSurveyHawaii.com
Robert J. "Bob" Dupuis
Marine Surveyor/Consultant